N,N,N′,N′-Tetrabenzyl-N′′-(2,6-difluorobenzoyl)phosphoric triamide
نویسندگان
چکیده
منابع مشابه
N,N′-Dicyclohexyl-N′′,N′′-dimethylphosphoric triamide
In the title compound, C(14)H(30)N(3)OP, both cyclo-hexyl groups adopt chair conformations with the NH unit in an equatorial position. The P atom adopts a slightly distorted tetra-hedral environment. In the (CH(3))(2)NP(O) unit, the O-P-N-C torsion angles, showing the orientations of the methyl groups with respect to the phosphoryl group, are -166.6 (3) and 34.6 (4)°. The O atom of the P=O grou...
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The P atom in the title mol-ecule, C(12)H(26)N(3)OP, has a distorted tetra-hedral configuration: its bond angles lie in the range 101.1 (2)-119.1 (2)°. The P-N bonds to the two cyclo-pentyl-amido moieties are significantly different [1.619 (4) and 1.643 (4) Å], with the shorter bond related to an anti orientation of the lone electron pair of the corresponding N atom relative to the P=O bond. Th...
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In the title compound, C(14)H(18)N(3)OP, a crystallographic mirror plane bis-ects the mol-ecule (the C,N,C atoms of the dimethyl-amido moiety and the P=O unit lie on the mirror plane). The P atom has a distorted tetra-hedral geometry; the bond angles at P are in the range 98.98 (11)-115.28 (7)°. In the crystal, the O atom of the P=O group acts as a double hydrogen-bond acceptor for two symmetry...
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The asymmetric unit of the title phospho-ric triamide, C13H21FN3O2P, consists of two independent mol-ecules. In each mol-ecule, the P=O group and the N-H unit belonging to the C(O)NHP(O) fragment are in a syn conformation with respect to each other. An intra-molecular N-H⋯O hydrogen bond occurs in each mol-ecule. The P atom adopts a distorted tetra-hedral environment. The methyl groups of an is...
متن کاملN-Benzoyl-N′,N′′-dicyclohexylphosphoric triamide
In the title compound, C(19)H(30)N(3)O(2)P, the central P atom has a distorted tetra-hedral configuration. The N atoms in both cyclo-hexyl-amide moieties exhibit a slight deviation [0.32 (7) and 0.44 (6) Å] from planarity, while the benzoyl-amide N atom is planar [0.11 (3) Å]. In the crystal, mol-ecules are linked via N-H⋯O(P) and N-H⋯O(C) hydrogen bonds, forming R(2) (2)(10) rings within linea...
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ژورنال
عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online
سال: 2012
ISSN: 1600-5368
DOI: 10.1107/s1600536812042481